Sec Form 4 Filing - OBRIEN THOMAS H @ PNC FINANCIAL SERVICES GROUP INC - 2006-08-04

FORM 4 Check this box if no longer subject to Section 16. Form 4 or Form 5 obligations may continue. See Instruction 1(b).

UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 STATEMENT OF CHANGES IN BENEFICIAL OWNERSHIP Filed pursuant to Section 16(a) of the Securities Exchange Act of 1934, Section 17(a) of the Public Utility Holding Company Act of 1935 or Section 30(h) of the Investment Company Act of 1940

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1. Name and Address of Reporting Person OBRIEN THOMAS H 2. Issuer Name and Ticker or Trading Symbol PNC FINANCIAL SERVICES GROUP INC [ PNC] 5. Relationship of Reporting Person(s) to Issuer (Check all applicable) X __ Director _____ 10% Owner _____ Officer (give title below) _____ Other (specify below) (Last) (First) (Middle) ONE PNC PLAZA, 249 FIFTH AVENUE 3. Date of Earliest Transaction (MM/DD/YY) 08/04/2006 (Street) PITTSBURGH, PA15222-2707 4. If Amendment, Date Original Filed (MM/DD/YY) 6. Individual or Joint/Group Filing (Check Applicable Line) __ X __ Form filed by One Reporting Person _____ Form filed by More than One Reporting Person (City) (State) (Zip)

Table I - Non-Derivative Securities Acquired, Disposed of, or Beneficially Owned 1.Title of Security (Instr. 3) 2. Transaction Date (MM/DD/YY) 2A. Deemed Execution Date, if any (MM/DD/YY) 3. Transaction Code (Instr. 8) 4. Securities Acquired (A) or Disposed of (D) (Instr. 3, 4 and 5) 5. Amount of Securities Beneficially Owned Following Reported Transaction(s) (Instr. 3 and 4) 6. Ownership Form: Direct (D) or Indirect (I) (Instr. 4) 7. Nature of Indirect Beneficial Ownership (Instr. 4) Code V Amount (A) or (D) Price $5 Par Common Stock 08/04/2006 M 52,250 A $ 50.47 193,160 D $5 Par Common Stock 08/04/2006 S( 1 ) 9,200 D $ 71.37 183,960 D $5 Par Common Stock 08/04/2006 S( 1 ) 300 D $ 71.38 183,660 D $5 Par Common Stock 08/04/2006 S( 1 ) 2,400 D $ 71.39 181,260 D $5 Par Common Stock 08/04/2006 S( 1 ) 28,900 D $ 71.4 152,360 D $5 Par Common Stock 08/04/2006 S( 1 ) 200 D $ 71.41 152,160 D $5 Par Common Stock 08/04/2006 S( 1 ) 300 D $ 71.42 151,860 D $5 Par Common Stock 08/04/2006 S( 1 ) 2,300 D $ 71.43 149,560 D $5 Par Common Stock 08/04/2006 S( 1 ) 2,200 D $ 71.44 147,360 D $5 Par Common Stock 08/04/2006 S( 1 ) 2,900 D $ 71.47 144,460 D $5 Par Common Stock 08/04/2006 S( 1 ) 2,550 D $ 71.48 141,910 D $5 Par Common Stock 08/04/2006 S( 1 ) 1,000 D $ 71.49 140,910 ( 2 ) D $5 Par Common Stock 3,971 ( 3 ) I 401(k) Plan

Table II - Derivative Securities Acquired, Disposed of, or Beneficially Owned ( e.g. , puts, calls, warrants, options, convertible securities) 1. Title of Derivative Security (Instr. 3) 2. Conversion or Exercise Price of Derivative Security 3. Transaction Date (MM/DD/YY) 3A. Deemed Execution Date, if any (MM/DD/YY) 4. Transaction Code (Instr. 8) 5. Number of Derivative Securities Acquired (A) or Disposed of (D) (Instr. 3, 4, and 5) 6. Date Exercisable and Expiration Date (MM/DD/YY) 7. Title and Amount of Underlying Securities (Instr. 3 and 4) 8. Price of Derivative Security (Instr. 5) 9. Number of Derivative Securities Beneficially Owned Following Reported Transaction(s) (Instr. 4) 10. Ownership Form of Derivative Security: Direct (D) or Indirect (I) (Instr. 4) 11. Nature of Indirect Beneficial Ownership (Instr. 4) Code V (A) (D) Date Exercisable Expiration Date Title Amount or Number of Shares Employee Stock Option (Right-to-Buy) $ 50.47 08/04/2006 M 52,250 02/17/2002 02/17/2009 $5 Par Common Stock 52,250 $ 0 0 D Phantom Stock Unit ( 4 ) 06/30/2006 J( 5 ) V 312 ( 6 ) ( 6 ) $5 Par Common Stock 312 $ 69.6 41,276 I Supplemental Incentive Savings Plan Phantom Stock Unit ( 4 ) ( 6 ) ( 6 ) $5 Par Common Stock 5,189 5,189 I Deferred Stock Unit Plan

Reporting Owners Reporting Owner Name / Address Relationships Director 10% Owner Officer Other OBRIEN THOMAS H ONE PNC PLAZA 249 FIFTH AVENUE PITTSBURGH, PA15222-2707 X Signatures George P. Long, Attorney-in-Fact for Thomas H. O'Brien 08/08/2006 Signature of Reporting Person Date

Explanation of Responses:

( 1 )Sale pursuant to cashless exercise of employee stock options. ( 2 )Since the date of the Reporting Person's last ownership report, he transferred 140,831 shares of PNC common stock to his former spouse pursuant to a domestic relations order. The reporting person no longer reports as beneficially owned any securities owned by his former spouse. ( 3 )Since the date of the Reporting Person's last ownership report, he transferred 6,673 shares of PNC common stock to his former spouse pursuant to a domestic relations order. The reporting person no longer reports as beneficially owned any securities owned by his former spouse. ( 4 )1 for 1. ( 5 )Phantom Stock Units received as dividend equivalents under the PNC Supplemental Incentive Savings Plan. ( 6 )Phantom Stock Units will be settled in cash upon distribution from the reporting person's plan account and generally do not expire.

Reminder: Report on a separate line for each class of securities beneficially owned directly or indirectly.

* If the form is filed by more than one reporting person, see Instruction 4(b)(v).

** Intentional misstatements or omissions of facts constitute Federal Criminal Violations. See 18 U.S.C. 1001 and 15 U.S.C. 78ff(a).

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